Note that player (or opponent as it references to opposing player) and hero are two different entities. One in in reference to the Hero card type on the playing field while the other specifies you as the player.
Certain cards actually target players. While the more common cards such as Hammer of Justice do target the hero, a fair bit of cards such as Eye of Kilrog (and a number of priest cards) references to the player. As such, Blessing of Freedom and Blessing of Salvation provides different functionality.
As Volcanic Lair targets a hero, you have to use Blessing of Freedom to interrupt its effect. Note that Garr has a power which targets an opponent (opposing player) which can be interrupted by Blessing of Salvation.
Some people learn, some people don't. For me, I can never correct myself to say Julia Graves as opposed to Julia Roberts